Study of the growth of strontium vanadate by solid-state dewetting: mechanisms and correlations with luminescence.

Project description

The development of new light-emitting diodes (LEDs) based on innovative materials meets major technological, economic and environmental challenges. Current LEDs, although efficient, have limitations linked to the use of expensive and sometimes rare materials, the extraction of which can have a significant environmental impact. In addition, optimising LED performance, particularly in terms of energy efficiency, thermal stability, durability and colour rendering, requires ongoing exploration of new materials.

Nanomaterials offer unique optical and electronic properties, such as tunable luminescence, high quantum efficiency and the ability to cover a wide colour spectrum. These characteristics make it possible to meet growing needs in areas such as high-efficiency lighting, high-resolution displays and wearable technologies. In addition, the development of non-toxic and easily recyclable materials is part of a sustainability approach that is essential in the face of today's environmental challenges. The integration of these new materials into LEDs promises to improve their performance while reducing their ecological impact, contributing to a transition towards more environmentally-friendly technologies.

Problematic

The aim of this thesis project is to continue work on the white light emission of strontium vanadate complexes for the development of new LEDs, as part of the ANR LEDVAN project currently underway between the GPM in Rouen, CIMAP and CRISMAT in Caen. Recent work between these partners has highlighted the particularly interesting properties of these materials (CMOS-compatible crystal growth, optical and electrical properties, transparent and conductive oxide properties) for such developments.

However, very few studies have been carried out on these materials, and to date there is no literature that adequately describes the experimental observations, particularly on the growth mechanism. Our recent work has revealed a strong disparity in the nanostructures observed after processing, depending on the initial thickness of the thin film: ranging from the presence of nanometric islands to homogeneous films, via agglomerates of grains. The associated luminescence is partially correlated with the nanostructure obtained. It is therefore essential to understand the influence of processing parameters (thickness, annealing, etc.) in order to optimise luminescence (colour and intensity).

Profile required:

The candidate should hold a Master's degree in Physics, Materials Science or Nanosciences. The candidate should have knowledge of materials science and solid state physics, and a particular interest in experimentation. Knowledge of the optical properties of semiconductor and/or oxide materials would be highly appreciated.

Contact :

Interested candidates should send the following documents

- Detailed CV

- Letter of motivation

- Transcripts of marks from Licence 3, Master 1 and Master 2.

Etienne Talbot – etienne.talbot@univ-rouen.fr, 02.32.95.51.32